Title:
有機金属錯体触媒
Document Type and Number:
Japanese Patent JPWO2018105672
Kind Code:
A1
Abstract:
クロスカップリング反応において従来の触媒よりも目的物の高い収率を得ることのできる有機金属錯体の提供。有機金属錯体触媒は式（１）で表される構造を有しクロスカップリング反応に使用される。式（１）中、Ｍは配位中心でありＰｄ等の金属の原子又はそのイオンを示す。Ｒ１、Ｒ２及びＲ３は同一であっても異なっていてもよく、水素原子等の置換基である。Ｒ４、Ｒ５、Ｒ６、及びＲ７は同一であっても異なっていてもよく、水素原子等の置換基である。Ｘはハロゲン原子を示す。Ｒ８はπ結合を有する炭素数３〜２０の置換基を示す。ただし、Ｒ１〜Ｒ７は、これらを含む式（２）の配位子の配位中心Ｍに対する電子供与性について、赤外分光法から得られるＴＥＰ値が、式（２−１）の配位子のＴＥＰ値と比較して低波数側へシフトするように組合せられて配置されている。【化１】
Inventors:
Choi Jun Satoshi
Norihisa Fukaya
Toshiya Onozawa
Kazuhiko Sato
Hiroyuki Yasuda
Mizusaki Tomoe
Yukio Takagi
Norihisa Fukaya
Toshiya Onozawa
Kazuhiko Sato
Hiroyuki Yasuda
Mizusaki Tomoe
Yukio Takagi
Application Number:
JP2018555050A
Publication Date:
October 24, 2019
Filing Date:
December 06, 2017
Export Citation:
Assignee:
National Institute of Advanced Industrial Science and Technology
NE Chemcat Co., Ltd.
NE Chemcat Co., Ltd.
International Classes:
B01J31/22; B01J37/04; C07F7/10; C07F15/00; C07F19/00
Foreign References:
| WO2007017047A1 | 2007-02-15 | |||
| WO2007017041A1 | 2007-02-15 |
Other References:
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