Title:
有機金属錯体及びその製造方法
Document Type and Number:
Japanese Patent JP5227992
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To obtain an organometallic complex that adsorbs and releases a relatively large amount of hydrogen within a temperature range of around room temperature.SOLUTION: The organometallic complex, [Cu(pyridine-3, 5-dicarboxylate)], is formed by successively connecting a plurality of recurring units, Cu(pyridine-3, 5-dicarboxylate). The unit cell of the organometallic complex has a crystal system belonging to the orthorhombic system. In the planar structure in the organometallic complex, there exist a plurality of cavities (spaces) where atoms are not densely packed. The cavity has a pore shape with an opening diameter and an inner diameter of several angstrom each, and a Cu atom, an O atom and an N atom are exposed on the inner surface thereof. This cavity functions as a hydrogen-adsorbing site.
Inventors:
Hiroshi Sakai
Kanoya
Terumi Furuta
Hikaru Hosoe
Kanoya
Terumi Furuta
Hikaru Hosoe
Application Number:
JP2010081296A
Publication Date:
July 03, 2013
Filing Date:
March 31, 2010
Export Citation:
Assignee:
Honda motor industry stock company
International Classes:
C07D213/80; C07F1/08; C08G79/00; B01J20/22
Domestic Patent References:
| JP2010180199A | ||||
| JP200935493A | ||||
| JP2007277106A | ||||
| JP2000202283A | ||||
| JP2008184533A |
Other References:
Lu, Jack Y.; Babb, Amy M.,A Simultaneous Reduction, Substitution, and Self-Assembly Reaction under Hydrothermal Conditions Afforded the First Diiodopyridine Copper(I) Coordination Polymer,Inorganic Chemistry,米国,2002年 3月25日,Vol.41 No.6,1339-1341
Attorney, Agent or Firm:
Takehiro Chiba
Toshiyuki Miyadera
Shuji Ouchi
Toshiyuki Miyadera
Shuji Ouchi