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Patent Searching and Data


Title:
OXIDATION OF 2-CHLOROPROPIONALDEHYDE
Document Type and Number:
Japanese Patent JPS63313747
Kind Code:
A
Abstract:

PURPOSE: To obtain 2-chloropropionic acid at a low cost, by using a rhenium compound, a ruthenium compound or a rhodium compound as a catalyst in a liquid-phase oxidation of 2-chloropropionaldehyde with oxygen or an oxygen- containing gas.

CONSTITUTION: The objective 2-chloropropionic acid having wide applications as an intermediate for industrial chemicals and agricultural chemicals is produced by oxidizing 2-chloropropionaldehyde with oxygen or an oxygen-containing gas in liquid phase in the presence of at least one kind of metallic compound catalyst selected from a rhenium compound, a ruthenium compound and a rhodium compound preferably at 20W120°C, especially at 40W80°C. The objective compound can be easily produced in high purity and efficiency in an environment having little corrosivity under an easily controllable oxidation condition while suppressing the by-production of peracid, etc.


Inventors:
ONO HIROSHI
KASUGA TAKAHARU
KIYONO SHINJI
Application Number:
JP14789087A
Publication Date:
December 21, 1988
Filing Date:
June 16, 1987
Export Citation:
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Assignee:
MITSUI TOATSU CHEMICALS
International Classes:
B01J23/36; B01J27/053; B01J27/10; B01J27/25; C07B61/00; C07C51/00; C07C51/235; C07C53/19; C07C67/00; (IPC1-7): B01J23/36; B01J27/053; B01J27/10; B01J27/25; C07C51/235; C07C53/19