Title:
【発明の名称】アルカンをアルケンに接触脱水素化し同時に水素を燃焼させる方法
Document Type and Number:
Japanese Patent JPH11503753
Kind Code:
A
Abstract:
There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is passed into a reactor containing both an equilibrium dehydrogenation catalyst and a reducible metal oxide, whereby the alkane is dehydrogenated and the hydrogen produced is simultaneously and selectively combusted in oxidation/ reduction (REDOX) reaction with the reducible metal oxide. This particular mode of operation is termed a same reactor, REDOX mode. The equilibrium dehydrogenation catalyst may comprise platinum and the reducible metal oxide may contain bismuth, antimony, indium, or molybdenum, or a mixture thereof.
Inventors:
Agascar, Prajot Adwaitanan
Robert Curl, Grasserie
Michaels, james nathaniel
Reishman, Paul Thomas
Stern, david lawrence
Zikoyanis, John George
Robert Curl, Grasserie
Michaels, james nathaniel
Reishman, Paul Thomas
Stern, david lawrence
Zikoyanis, John George
Application Number:
JP53168896A
Publication Date:
March 30, 1999
Filing Date:
June 06, 1995
Export Citation:
Assignee:
MOBIL OIL CORPORATION
International Classes:
B01J23/06; B01J23/08; B01J23/10; B01J23/14; B01J23/18; B01J23/20; B01J23/22; B01J23/28; B01J23/30; B01J23/31; B01J23/745; B01J23/88; B01J27/199; B01J29/44; C07C5/333; C07C5/42; C07C11/02; (IPC1-7): C07C11/02; B01J23/06; B01J23/08; B01J23/10; B01J23/14; B01J23/18; B01J23/20; B01J23/22; B01J23/28; B01J23/30; B01J23/31; B01J23/745; B01J23/88; B01J27/199; B01J29/44; C07C5/333
Domestic Patent References:
| JPS4703412A | ||||
| JPS6020987A | 1985-02-02 | |||
| JPH02311425A | 1990-12-27 |
Foreign References:
| US4327238A | 1982-04-27 |
Attorney, Agent or Firm:
Nao Okuyama (3 others)