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Title:
パラジウムの抽出剤及びそれを用いた迅速分離回収方法
Document Type and Number:
Japanese Patent JP5299962
Kind Code:
B2
Abstract:
Provided is a novel extractant for palladium capable of improving an extraction rate compared to the conventional extractant, DHS, and also capable of back-extracting palladium using an ammonia solution, and a method of separating and recovering palladium using the novel extractant. The present invention provides a method for obtaining an aqueous solution containing palladium only by: bringing an acidic aqueous solution containing at least palladium into contact with an organic solution containing a sulfide-containing monoamide as an active integredient represented by the following structural formula (I), where R1, R2, and R3 each represent a group selected from a chain hydrocarbon group having 1 to 18 carbon atoms which may be branched, an alicyclic hydrocarbon group having 1 to 10 carbon atoms, and an aromatic hydrocarbon group having 1 to 14 carbon atoms, and n represents an integer of 1 to 4; extracting palladium into the organic solution; and conducting the back-extraction of the palladium extracted in the organic solution to an aqueous solution using an ammonia solution.

Inventors:
Koichi Narita
Mikiya Tanaka
Ken Tamura
Application Number:
JP2009006341A
Publication Date:
September 25, 2013
Filing Date:
January 15, 2009
Export Citation:
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Assignee:
National Institute of Advanced Industrial Science and Technology
International Classes:
C22B11/00; B01D11/04; C07C323/60; C22B3/26; C22B7/00
Domestic Patent References:
JP61041728A
JP61238927A
JP3253524A
JP2005146326A
Foreign References:
WO2005083131A1