Title:
PHOSPHINE-OLEFIN LIGAND HAVING FACE ASYMMETRIC CYCLOPENTADIENYL-MANGANESE COMPLEX IN BASIC SKELETON
Document Type and Number:
Japanese Patent JP2017008013
Kind Code:
A
Abstract:
PROBLEM TO BE SOLVED: To provide a face asymmetric ligand for a transition metal catalyst asymmetric reaction high in yield and optical purity to not only a cyclic enone compound, but also various enone compounds containing an aliphatic enone compound.SOLUTION: The above described problem is solved by (+) or (-)-((η-1-phosphino-2-propenyl)cyclopentadienyl-P)manganese (I) dicarbonyl compound represented by the following general formula (7), where R is a Cto Calkyl group of an aryl group may be optionally substituted by a Cto Calkyl group, R' is a hydrogen atom, a Cto Calkyl group which may be optionally substituted by an aryl group or an aryl group which may be optionally substituted by a Cto Calkyl group, R'' is a Cto Calkyl group or an aryl group which may be optionally substituted by a Cto Calkyl group.SELECTED DRAWING: None
Inventors:
KAMIKAWA KEN
TSENG YA-YI
OGASAWARA MASAMICHI
TAKAHASHI TAMOTSU
TSENG YA-YI
OGASAWARA MASAMICHI
TAKAHASHI TAMOTSU
Application Number:
JP2015128291A
Publication Date:
January 12, 2017
Filing Date:
June 26, 2015
Export Citation:
Assignee:
UNIV OSAKA PREFECTURE
UNIV HOKKAIDO
UNIV HOKKAIDO
International Classes:
C07F19/00; B01J31/24; C07C45/69; C07C49/213; C07C49/67; C07C49/697; C07F9/50; C07F17/00
Domestic Patent References:
| JP2004537583A | 2004-12-16 |
Other References:
ANGEWANDTE CHEMIE, INTERNATIONAL EDITION, vol. 51, no. 12, JPN6019009922, 2012, pages 2951 - 2955, ISSN: 0004002043
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 136, no. 26, JPN6019009924, 2014, pages 9377 - 9384, ISSN: 0004002044
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 136, no. 26, JPN6019009924, 2014, pages 9377 - 9384, ISSN: 0004002044
Attorney, Agent or Firm:
Shintaro Nogawa
Shinji Kai
Yusuke Kaneko
Kiyoshi Inamoto
Shinji Kai
Yusuke Kaneko
Kiyoshi Inamoto