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Title:
PHOSPHINOFERROCENE GROUP-CONTAINING OLIGOMER
Document Type and Number:
Japanese Patent JP2012188386
Kind Code:
A
Abstract:

To provide a phosphinoferrocene group-containing oligomer usable as a component for a catalyst for amination reaction or the like, and to provide a reusable, inexpensive and heterogeneous catalyst containing the oligomer and a transition metal, usable for the amination reaction or the like, and capable of being readily recovered.

The phosphinoferrocene group-containing oligomer has a repeating unit containing a polyol-dehydrated residue bonded to the phosphinoferrocene group, and the oligomer is formed by the repeat of the repeating unit and has a number average molecular weight of 1,000-10,000. The heterogeneous catalyst contains the phosphinoferrocene group-containing oligomer and the transition metal with which the oligomer coordinates, and is insoluble in a solvent.


Inventors:
SHIMADA TOYOJI
KAMEI TOSHIYUKI
HOSOI HIROYUKI
AOKI MASARU
TAKAMATSU YOSHINORI
Application Number:
JP2011053421A
Publication Date:
October 04, 2012
Filing Date:
March 10, 2011
Export Citation:
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Assignee:
SHIMADA TOYOJI
KAMEI TOSHIYUKI
KYOEISHA CHEMICAL
International Classes:
C07F19/00; B01J31/24; C07C209/10; C07C211/58; C07F9/50; C07F17/02; C08G61/12
Attorney, Agent or Firm:
大西 浩之
小宮 良雄