Title:
パイ電子系拡張ビオローゲン誘導体とポルフィリンとの超分子錯体を用いる光電荷分離
Document Type and Number:
Japanese Patent JP4201339
Kind Code:
B2
Abstract:
Long-lived charge separation is attained with high efficiency by using a supramolecular complex utilizing pi-pi interaction. A supramolecular complex is formed by pi-pi interaction between extended viologen, the extended viologen having heteroaryls coupled together by a linking group with pi-electron conjugated system, and porphyrin. As a result of study of photoelectron transfer reaction, it has been found that within the supramolecular complex, efficient electron transfer occurs from the singlet excited state of porphyrin to the extended viologen, thereby obtaining a charge separation condition of extremely long lifetime exceeding 1 millisecond.
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Inventors:
Shunichi Fukuzumi
Application Number:
JP2004068247A
Publication Date:
December 24, 2008
Filing Date:
March 10, 2004
Export Citation:
Assignee:
Japan Science and Technology Agency
International Classes:
C07D213/53; C07D215/12; B01J31/28; B01J35/00; C01B3/02; C01B3/04; C07D487/22; H01L31/04; H01L51/42; H01M14/00
Domestic Patent References:
| JP4000310B2 | ||||
| JP2001097977A | ||||
| JP6148793A |
Other References:
園田 純子など,短いスペーサーで連結されたポルフィリン・フラーレン分子の光物性,2001年光化学討論会・21世紀の光化学国際会議要旨集,吉原經太郎,2001年 9月 3日,第390頁,要旨番号3P33
USHAKOV,E.N. et al,Ultrafast excited state dynamics of the bi- and termolecular stilbene-viologen charge-transfer complexes assembled via host-guest interactions,Chemical Physics,2004年 3月 8日,Vol.298, No.1-3,p.251-261
Evgeny KAGANER et al.,Photoinduced Electron Transfer in π-Donor-Capped Zn(II) Porphyrins and N,N'-Dimethyl-4,4'-bipyridinium Supramolecular Assemblies,J. Phys. Chem. B,1998年 1月22日,vol.102, no.7,p.1159-1165
J. A. SHELNUTT,Electronic Structure of the Porphyrin Ring in an Electrostatically Bound π-π Complex. Methylviologen-Metallouroporphyrin Complexes,J. Phys. Chem.,1984年,vol.88, no.25,p.6121-6127
藤本 香名など,新しい機能を持つ酸化還元イオン対化合物の開発と光応答,静岡大学電子工学研究所研究報告,1999年,第34巻,第15~21頁
USHAKOV,E.N. et al,Ultrafast excited state dynamics of the bi- and termolecular stilbene-viologen charge-transfer complexes assembled via host-guest interactions,Chemical Physics,2004年 3月 8日,Vol.298, No.1-3,p.251-261
Evgeny KAGANER et al.,Photoinduced Electron Transfer in π-Donor-Capped Zn(II) Porphyrins and N,N'-Dimethyl-4,4'-bipyridinium Supramolecular Assemblies,J. Phys. Chem. B,1998年 1月22日,vol.102, no.7,p.1159-1165
J. A. SHELNUTT,Electronic Structure of the Porphyrin Ring in an Electrostatically Bound π-π Complex. Methylviologen-Metallouroporphyrin Complexes,J. Phys. Chem.,1984年,vol.88, no.25,p.6121-6127
藤本 香名など,新しい機能を持つ酸化還元イオン対化合物の開発と光応答,静岡大学電子工学研究所研究報告,1999年,第34巻,第15~21頁
Attorney, Agent or Firm:
Hidesaku Yamamoto
Takaaki Yasumura
Natsuki Morishita
Takaaki Yasumura
Natsuki Morishita
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