Title:
PLANAR CHIRAL METALLOCENE RING-FUSED CARBENE AND PRODUCTION METHOD THEREFOR, AND METAL COMPLEX WITH THE DERIVATIVE AS LIGAND
Document Type and Number:
Japanese Patent JP2018035131
Kind Code:
A
Abstract:
PROBLEM TO BE SOLVED: To provide a planar chiral carbene ligand which is easily synthesized.SOLUTION: There is provided a carbene which can be synthesized from a planar chiral iminium salt derivative of the formula (1), where Rto Rare H, a substituted/unsubstituted Cto Chydrocarbon group, a substituted/unsubstituted Cto Calkoxy group, a substituted/unsubstituted Cto Caryloxy group, a substituted/unsubstituted amino group, a substituted/unsubstituted phosphino group, a substituted/unsubstituted silyl group, a substituted/unsubstituted alkylthio group or a substituted/unsubstituted arylthio group or the like; X is a substituted/unsubstituted Cto Ccarbon atom or a substituted/unsubstituted atomic group consisting of N, O, S or any combination of these hetero atoms and a carbon atom which may have a substituent; Z is a halogen atom, PF, BF, ClOor BPh; and M is a transition atom such as Fe and Ru. Although the formula (1) represents one of two enantiomers of planar chiral compound, it may be another enantiomer.SELECTED DRAWING: None
Inventors:
YOSHIDA KAZUHIRO
YASUE RISA
MIYAUCHI MASARU
SHIKATA YUTA
YASUE RISA
MIYAUCHI MASARU
SHIKATA YUTA
Application Number:
JP2017016369A
Publication Date:
March 08, 2018
Filing Date:
January 31, 2017
Export Citation:
Assignee:
UNIV CHIBA NAT UNIV CORP
International Classes:
C07F19/00; B01J31/22