To provide a polyimide resin composite flexible sheet used for obtaining a polyimide composite flexible sheet, which is excellent in stickiness, mechanical properties, heat resistance and size stability, and having no warpage or bending problem, without using a pressure-sensitive adhesive, and its manufacturing method.
A polyamic acid of which the coefficient of thermal expansion (CTE) after cyclization is larger than 20 ppm and a polyamic acid of which the thermal expansion (CTE) after cyclization is smaller than 20 ppm are applied to the surface of a metal foil sequentially and the polyamic acids are subsequently cyclized by heating to form a polyimide. By this method, the polyimide resin composite soft sheet for a printed circuit board is manufactured.
TU AN PANG
WU SHENG YEN
LIN TE YU
Shinsuke Nakajima
Atsushi Tadokoro