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Title:
ビスマス-ジチオカルボキシレート錯体構造を有するポリマーおよびフッ化物イオン検出用剤
Document Type and Number:
Japanese Patent JP7426074
Kind Code:
B2
Abstract:
To provide a pi-electron conjugated polymer having a bismuth-dithiocarboxylate complex structure introduced in a main chain, the polymer having an extended conjugation length and having a novel electronic structure and a unique optical property.SOLUTION: Provided is a polymer having a bismuth-dithiocarboxylate complex structure represented by the following general formula (1). (In the general formula (1), Ar1 represents an aryl group which may have a substituent or a heteroaryl group which may have a substituent; Ar2 represents one or mutually connected two or more arylene group(s) or heteroarylene group(s); R represents a C1-200 linear or branched alkyl group or alkoxy group, which may contain one or more oxygen atom(s) in a chain; m represents an integer of 0 to 30; and n represents an integer of 1 to 1000.)SELECTED DRAWING: None

Inventors:
Yoshimasa Matsumura
Naoki Usui
Bungo Ochiai
Application Number:
JP2020037066A
Publication Date:
February 01, 2024
Filing Date:
March 04, 2020
Export Citation:
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Assignee:
Yamagata University
International Classes:
G01N31/22; C08G79/00
Domestic Patent References:
JP2017020904A
Other References:
KIMURA, Mitsutoshi et al.,Synthesis, Structures, and Some Reactions of [(Thioacyl)thio]- and (Acylseleno)antimony and -bismuth Derivatives,HELVETICA CHIMICA ACTA,2006年04月19日,Volume 89,747-783
CHAUDHARI, K. R. et al.,Monoorganobismuth(III) dithiocarboxylates: Synthesis, structures and their utility as molecular precursors for the preparation of Bi2S3 films and nanocrystals,Inorganica Chimica Acta,Volume 363,2010年01月15日,375-380
Attorney, Agent or Firm:
Shigeru Kinoshita
Yuko Sawada