To provide an addition polymerization catalyst component and an addition polymerization catalyst, used in manufacturing an addition polymer high in melt tension and excellent in processability; and to provide a method for manufacturing an addition polymer high in melt tension and excellent in processability.
The polymerization catalyst for ethylene and α-olefin is prepared by bringing an olefin polymerization catalyst component including a transition metal compound of (i) and a transition metal compound of (ii) into contact with an activating cocatalyst component and an organoaluminum compound: (i) A transition metal compound which has two groups having a cyclopentadienic anion skeleton, the two groups being bonded to each other directly or through a crosslinking group, and has hafnium as a central metal; (ii) A transition metal compound which has two groups having a cyclopentadienic anion skeleton having a substituent, the two groups not being bonded to each other, and has zirconium as a central metal.
TAKAOKI KAZUO
JP2003082018A | 2003-03-19 | |||
JP2001181320A | 2001-07-03 | |||
JPH04213305A | 1992-08-04 | |||
JPH06298824A | 1994-10-25 | |||
JPS60217209A | 1985-10-30 |
Toru Sakamoto