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Title:
POLYMERIZATION OF VINYL CHLORIDE MONOMER
Document Type and Number:
Japanese Patent JPH09302003
Kind Code:
A
Abstract:

To provide a method of polymerizing a vinyl chloride monomer by batchwise suspension polymerization, wherein defective stirring can be prevented when vinyl chloride monomer is additionally charged, less fish eyes are formed in spite of a high bulk specific gravity, and a vinyl chloride monomer excellent in workability can be obtained.

In suspension polymerization by charging, into a polymerization vessel, a vinyl chloride monomer comprising vinyl chloride monomer singly or a monomer composition mainly made up of vinyl chloride monomer together with an aqueous medium, a dispersant, and a polymerization initiator, vinyl chloride monomer and a polyethylene oxide having an average molecular weight of 100,000 to 12,000,000 are added with the amount of the polyethylene oxide being 0.002 to 0.2wt.% based on the vinyl chloride monomer when the polymerization conversion of the vinyl chloride monomer to a polymer during the polymerization reaction is 20 to 80%.


Inventors:
YOSHITOMI HIDEAKI
TANAKA BUNJI
Application Number:
JP11755696A
Publication Date:
November 25, 1997
Filing Date:
May 13, 1996
Export Citation:
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Assignee:
SEKISUI CHEMICAL CO LTD
TOKUYAMA SEKISUI IND CORP
International Classes:
C08L27/06; C08F2/00; C08F2/18; C08F2/44; C08F14/00; C08F14/06; C08L71/00; (IPC1-7): C08F2/00; C08F2/18; C08F2/44; C08F14/06; C08L27/06
Attorney, Agent or Firm:
九十九 高秋