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Title:
PREPARATION OF ANTHRAQUINONE
Document Type and Number:
Japanese Patent JPS57156432
Kind Code:
A
Abstract:

PURPOSE: To obtain the titled substance useful as an intermediate for synthesizing dye, etc. in high yield for a long time with preparing a small amount of by- products, by oxidizing a diphenylmethane or a benzophenone as a raw material using molybdenum oxide and titanium oxide as a catalyst.

CONSTITUTION: In oxidizing a diphenylmethane shown by the formulaI(R1 is 1W4C alkyl, formyl, carboxyl) or a benzophenone shown by the formula II (R2 is 1W4C alkyl, formyl, carboxyl) as a raw material, it is subjected to contact gaseous oxidation with an oxygen-containing gas in the presence of a catalyst comprising molybdenum oxide and titanium oxide at 200W700°C, preferaby 250W500°C, to give the desired compound. The catalyst may comprise an oxide of calcium, antimony, bismuth, chromium, etc. as a third component as well as molybdenum oxide and titanium oxide as the main components.


Inventors:
SUDOU ISAMU
KIYOURA TADAMITSU
Application Number:
JP4166981A
Publication Date:
September 27, 1982
Filing Date:
March 24, 1981
Export Citation:
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Assignee:
MITSUI TOATSU CHEMICALS
International Classes:
C07C50/18; B01J23/00; B01J23/28; C07B61/00; C07C45/00; C07C46/02; C07C67/00; (IPC1-7): B01J23/28; C07C46/02; C07C50/18
Domestic Patent References:
JPS57144236A1982-09-06