Title:
PREPARATION METHOD OF RUTHENIUM OR OSMIUM COMPLEX CONTAINING P AND N DONOR LIGANDS
Document Type and Number:
Japanese Patent JP2020023515
Kind Code:
A
Abstract:
To provide a method for large scale production of a ruthenium complex containing a P and N donor ligands.SOLUTION: There is provided a preparation method of a [M(X)(L)m(L)] complex including a process for reacting a phosphorus ligand L, a bidentate N,N ligand L, and a [M(X)(L)] complex in a ketone solvent to form a [M(X)(L)m(L)] complex. M is ruthenium or osmium; X is an anionic ligand; L is a tertiary phosphine ligand; Lis chiral or achiral monodentate phosphorus ligand phosphorus different from L, or chiral or achiral bidentate phosphorus ligand; m is 1 or 2; when m is 1, Lis the bidentate phosphorus ligand, when m is 2, each Lis monodentate phosphorus ligand; Lis a nitrogen-containing heteroaryl group, or a bidentate N,N ligand containing an amino group; and the ketone solvent is liquid ketone having boiling point of less than 160°C under ambient pressure of 1.0135×10Pa.SELECTED DRAWING: None
Inventors:
SARAH FACCHETTI
HANS NEDDEN
HANS NEDDEN
Application Number:
JP2019177010A
Publication Date:
February 13, 2020
Filing Date:
September 27, 2019
Export Citation:
Assignee:
JOHNSON MATTHEY PLC
International Classes:
C07F15/00; C07D213/38; C07D221/10; C07F9/50; C07F17/02
Domestic Patent References:
| JP2007536338A | 2007-12-13 | |||
| JP2016517847A | 2016-06-20 | |||
| JP6619337B2 | 2019-12-11 |
Other References:
BARATTA, W ET AL.: "Highly Diastereoselective Formation of Ruthenium Complexes for Efficient Catalytic Asymmetric Transf", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 46, JPN6018036241, 2007, pages 7651 - 7654, XP055163292, ISSN: 0004481997, DOI: 10.1002/anie.200702278
ARRAYAS, RG ET AL.: "Recent Applications of Chiral Ferrocene Ligands in Asymmetric Catalysis", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 45, JPN5016011700, 2006, pages 7674 - 7715, XP009098057, ISSN: 0004481998, DOI: 10.1002/anie.200602482
FOX, MA ET AL.: "A simple synthesis of trans-RuCl(C≡CR)(dppe)2 complexes and representative molecular structures", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 694, JPN6018036249, 2009, pages 2350 - 2358, XP026149390, ISSN: 0004339829, DOI: 10.1016/j.jorganchem.2009.03.033
ARRAYAS, RG ET AL.: "Recent Applications of Chiral Ferrocene Ligands in Asymmetric Catalysis", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 45, JPN5016011700, 2006, pages 7674 - 7715, XP009098057, ISSN: 0004481998, DOI: 10.1002/anie.200602482
FOX, MA ET AL.: "A simple synthesis of trans-RuCl(C≡CR)(dppe)2 complexes and representative molecular structures", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 694, JPN6018036249, 2009, pages 2350 - 2358, XP026149390, ISSN: 0004339829, DOI: 10.1016/j.jorganchem.2009.03.033
Attorney, Agent or Firm:
Sonoda/Kobayashi Patent Business Corporation