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Title:
PREPARATION OF POLYCYCLIC DYES AND INTERMEDIATE THEREFOR
Document Type and Number:
Japanese Patent JPH0687807
Kind Code:
A
Abstract:

PURPOSE: To advantageously prepare the polycyclic dyes useful for the coloration of synthetic textiles particularly polyester by using the new intermediates and reacting them with benzofuranone.

CONSTITUTION: The polycyclic dyes of formula III [e.g. 3-phenyl-7-[4-amino-3- ethyl-5-methylphenyl]-2,6-dioxo-2,6-dihydrobenzo[1:2-b,4:5-b']-difuran or the like] are obtained by reacting new compounds of formula I (R1 and R2 are each H or alkyl; R3 is alkyl; R4 is H or alkyl; R5 and R6 are each alkyl or link together with adjacent N to form a heteroalicyclic ring) with benzofuranones of formula II (ring A is unsubstituted or substituted by from 1 to 3 substituents under conditions which at least one of R1, R2 and R4 is H). The new compounds of formula I [e.g. 1-morpholino-1-[4-amino-3-ethyl-5-methylphenyl]-acetic acid or the like] is obtained by reacting anilines of formula IV with glyoxylic acid or compounds of formula V.


Inventors:
NAIJIERU HOORU
MAIKERU CHIYAARUZU HENRII SUTA
Application Number:
JP14339893A
Publication Date:
March 29, 1994
Filing Date:
June 15, 1993
Export Citation:
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Assignee:
ZENECA LTD
International Classes:
C07C229/36; C07C229/42; C07D493/04; C09B57/00; C07D295/14; (IPC1-7): C07C229/36; C07D493/04; C09B57/00
Attorney, Agent or Firm:
Toshio Yano (1 outside)