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Title:
PRODUCTION OF 2-PHENYLBENZOTRIAZOLE-N-OXIDE
Document Type and Number:
Japanese Patent JPS59172481
Kind Code:
A
Abstract:

PURPOSE: To obtain the titled compound which is an ultraviolet light absorber in high yield without problem in economy and pollution, by reducing an o-nitroazobenzene with a primary or secondary alcohol in the presence of a hydrogen transfer catalyst and a base.

CONSTITUTION: An o-nitroazobenzene of formula I (R1 is H, Cl atom, 1W4C lower alkyl, 1W4C lower alkoxyl, etc.; R2 is H, Cl atom, 1W4C lower alkyl or 1W4C lower alkoxyl; R3 is H, Cl atom, 1W12C alkyl, 1W4C lower alkoxyl, etc.; R4 is H, Cl atom, hydroxyl, etc.; R5 is H, 1W12C alkyl, etc.) is reduced with a chemical equivalent amount or more of a primary or secondary alcohol in the presence of a hydrogen transfer catalyst, e.g. anthraquinone, and a base and further preferably a phase transfer catalyst, surfactant or polyhydric alcohol to give the aimed compound of formula II.


Inventors:
SEINO SHIYUUICHI
Application Number:
JP4658883A
Publication Date:
September 29, 1984
Filing Date:
March 18, 1983
Export Citation:
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Assignee:
SEINO SHIYUUICHI
International Classes:
C07D249/20; B01J31/00; B01J31/02; C07B61/00; C09K3/00; (IPC1-7): B01J31/02; C07D249/20; C09K3/00
Domestic Patent References:
JPS5723347A1982-02-06
Attorney, Agent or Firm:
Tsukimura Shigeru