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Title:
PRODUCTION OF AROMATIC AMINE
Document Type and Number:
Japanese Patent JPH08176075
Kind Code:
A
Abstract:

To obtain, in high yield with long catalyst life and little byproducts, an aromatic amine useful as an intermediate for plant protectants by dehydrogenating an aliphatic amine in the presence of a specified heterogeneous catalyst at specified temperature and pressure.

This aromatic amine of formura II is obtained by dehydrogenation of (B) an aliphatic amine of formula I (R1 to R5 are each H, a 1-12C alkyl or a 3-12C cycloalkyl) in the presence of (A) a catalyst as a heterogeneous catalyst consisting of 30-100 wt.% (A1) Pd supported on a carrier consisting of oxides of rare earth metals or Group IVb oxides or (A2) Pt/Pd mixture supported on a carrier consisting of alumina, oxides of rare earth metals or Group IVb oxides, at 150-300°C under the pressure of 0.01-50 bar.


Inventors:
URURITSUHI KEERAA
FURANKUUFURIIDORITSUHI PAAPE
MATEIASU IRUGANGU
YOAHIMU BURUFUUDEERINGU
MIHIYAERU HETSUSE
PEETAA PORANEKU
Application Number:
JP20824495A
Publication Date:
July 09, 1996
Filing Date:
August 15, 1995
Export Citation:
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Assignee:
BASF AG
International Classes:
B01J23/42; B01J23/58; B01J23/63; C07B61/00; C07C209/16; C07C209/68; C07C209/72; C07C211/45; B01J23/40; (IPC1-7): C07C211/45; B01J23/40; B01J23/42; B01J23/63; B01J23/58; C07C209/68
Attorney, Agent or Firm:
Toshio Yano (2 outside)