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Title:
PRODUCTION OF AROMATIC POLYCARBONATE RESIN
Document Type and Number:
Japanese Patent JPH09183838
Kind Code:
A
Abstract:

To produce a resin excellent in moldability, heat stability, mold- corrosion resistance, etc., and useful for a formed article having a low birefringence such as an optical material by polymerizing specific two kinds of divalent phenols with a carbonic acid diester in molten state.

(A) An aromatic dihydroxy component whose at least 80mol% is (i) 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane and (ii) 2,-2bis(3-methyl-4- hydroxyphenyl)propane, wherein a ratio of the components (i) to (ii) is 99:1 to 20:80, preferably 80:20 to 20:80 in terms of molar ratio is polymerized with (B) a carbonic acid diester (preferably, diphenyl carbonate) in molten state. The melt polymerization is preferably carried out in the presence of a polymerization catalyst consisting of an alkali metal or alkaline earth metal compound and a nitrogen-containing basic compound.


Inventors:
TOKUDA TOSHIMASA
Application Number:
JP34319595A
Publication Date:
July 15, 1997
Filing Date:
December 28, 1995
Export Citation:
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Assignee:
TEIJIN CHEMICALS LTD
International Classes:
C08G64/06; C08G64/00; C08G64/20; C08G64/30; (IPC1-7): C08G64/30; C08G64/06
Attorney, Agent or Firm:
Masataka Oshima