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Title:
PRODUCTION OF BROMINE-CONTAINING EPOXY RESIN
Document Type and Number:
Japanese Patent JPS5774326
Kind Code:
A
Abstract:

PURPOSE: To produce the titled epoxy resin having low melt viscosity and being readily withdrawn from a reaction kettle, by reating specified two alkanes with an epihalohydrin and, then, dehydrohalogenating the product.

CONSTITUTION: A mixture (mol. ratio 1W4:1) of a bis(hydroxyphenyl)-alkane and a bromine-substituted 2,2-bis(4-hydroxyphenyl)alkane and an epihalohydrin in an amount of 3 times, by mol., as much as the mixture are subjected to an addition reaction at 30W90°C for 4W6hr in the presence of an addition catalyst, e.g., NaOH. Then, a dehydrohalogenating agent such as an alkali metal hydroxide is added to the reaction product, the resulting mixture is subjected to a dehydrohalogenation reaction at 60W90°C for several hr and the excess epihalohydrin and the formed alkali metal halide are removed to obtain a normally liquid, bromine-containing epoxy resin, bromine content ≥16wt%.


Inventors:
INNAMI HIDETOSHI
AKIYAMA SEIICHI
Application Number:
JP15013980A
Publication Date:
May 10, 1982
Filing Date:
October 28, 1980
Export Citation:
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Assignee:
ASAHI CHEMICAL IND
International Classes:
C08G59/00; C08G59/06; (IPC1-7): C08G59/06
Domestic Patent References:
JPS558626A1980-01-22
JPS5446649A1979-04-12
JPS54117266A1979-09-12
JPS54123354A1979-09-25
JPS5315958A1978-02-14



 
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