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Title:
PRODUCTION OF D-ARABITOL
Document Type and Number:
Japanese Patent JPH1087531
Kind Code:
A
Abstract:

To provide a method for producing D-arabitol, enabling to obtain the compound useful as an intermediate for synthesizing xylitol from a low cost raw material with a good yield, by hydrolyzing a lactose solution, oxidizing the hydrolysates, decarboxylating the oxidation products, and subsequently catalytically hydrogenating the products.

This method for producing D-arabitol comprises hydrolyzing a lactose solution by a chemical means or with an enzyme, oxidizing the obtained mixture of glucose with galactose with air or oxygen in the presence of a palladium catalyst in an alkaline medium or with a microorganism such as a Gluconobacter oxidizing agent ATCC 19357 or 23773, subjecting the obtained mixture of gluconic acid with galactonic acid to a decarboxylation reaction using hydrogen peroxide, and subsequently catalytically hydrogenating the obtained mixture of D-arabitol with D-lyxose in the presence of Raney nickel, etc.


Inventors:
DELOBEAU DIDIER
MOINE DIDIER
Application Number:
JP14060797A
Publication Date:
April 07, 1998
Filing Date:
May 29, 1997
Export Citation:
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Assignee:
ROQUETTE FRERES
International Classes:
B01J25/02; C07B61/00; C07C29/141; C07C29/145; C07C31/18; C12P7/40; C07C51/31; C07H3/02; C12P7/58; C12P19/14; C13K13/00; (IPC1-7): C07C31/18; B01J25/02; C07C29/145; C12P7/40
Attorney, Agent or Firm:
Masatake Shiga (2 outside)