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Title:
PRODUCTION OF HIGH-SOLID CONTENT SYNTHETIC RESIN EMULSION
Document Type and Number:
Japanese Patent JP2558392
Kind Code:
B2
Abstract:

PURPOSE: To enable simple production of synthetic resin emulsion which has excellent heat resistance, adhesion and high stability because of low viscosity despite high solid content, by effecting emulsion polymerization of vinyl monomer mixture using a reactive emulsifier in the presence of a specific coagulant.
CONSTITUTION: In the presence of a coagulant in an amount of 0.01 to 3wt.% of the total weight of a vinyl monomer mixture which comprises mainly acrylic acid esters and contains 0.1 to 12wt.% of unsaturated carboxylic acid, emulsion polymerization is effected using a reactive emulsifier represented by formulas I to V (R1, R3, R5 are hydrocarbon which may be substituted; R2, R4, R6 are hydrogen, methyl; M is Na, NH; A is 2 to 4 C alkylene; X is hydrogen, nonionic or anionic hydrophilic group; m is O to 100) to give a synthetic resin emulsion of 65 to 85wt.% solid content.


Inventors:
TSUKYAMA FUMITOSHI
NISHIIKE HARUKI
SHIMAZAKI SHIN
Application Number:
JP5392291A
Publication Date:
November 27, 1996
Filing Date:
February 26, 1991
Export Citation:
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Assignee:
SHOWA HIGHPOLYMER
International Classes:
C08F2/24; C08F12/00; C08F16/14; C08F16/16; C08F18/02; C08F212/14; C08F216/14; C08F216/16; C08F218/02; C08F220/10; C08F220/18; (IPC1-7): C08F220/10; C08F2/24
Domestic Patent References:
JP63254104A
JP62221431A
JP62104802A
JP6234927A
Attorney, Agent or Firm:
Yaguchi flat