PURPOSE: To produce the titled film having high electric conductivity, by coating the surface of a solid with a catalyst solution containing an electron-accepting compound or an electron-donating compound and bringing the surface into contact with acetylene gas.
CONSTITUTION: A solution of a Ziegler catalyst-type coordinated anionic polymerization catalyst (e.g., titanium tetrabutoxidetriethylaluminum system) containing an electron-accepting compound (e.g., tetracyano-p-quinodimethane) or an electron-donating compound (e.g., tetrathiafulvalene) is applied to the surface of the wall of a polymerization vessel or to a solid not reactive with the catalyst (e.g., glass) and then acetone, O2 and acetylene gas purified to ≤2ppm water content are introduced and reacted at -100W150°C to form a polyacetylene film on the surface of the solid.
| JPS57150429 | VACUUM REACTOR |
MATSUMURA TERUICHIROU
TSUKAMOTO JIYUN
DAITOU KOUJI
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