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Title:
PRODUCTION OF LOW-MOLECULAR WEIGHT POLYETHYLENE
Document Type and Number:
Japanese Patent JPS59142209
Kind Code:
A
Abstract:

PURPOSE: To produce a low-MW PE of good color without a step of catalyst removal, by (co)polymerizing ethylene under a specified condition in the presence of a catalyst system comprising a specified solid catalyst component and an organoaluminum compound.

CONSTITUTION: A solid catalyst component (A) is obtained by reacting (a) an oxygen-containing organic compound of Mg (e.g., magnesium diethoxide) with (b) a halide of Ti (e.g., TiCl4) or reacting component (a) with (c) an oxygen-containing organic compound (e.g., tetraethoxytitanium) and (d) a halide of Al (e.g., ethylaluminum dichloride) in an inert hydrocarbon solvent. Ethylene is polymerized or copolymerized with a small amount of an α-olefin in the presence of a catalyst system comprising component A and (B) an organoaluminum compound (e.g., triethylaluminum) in a saturated hydrocarbon solvent in the presence of hydrogen in an amount 1W30 times, by moles, that of ethylene at 120W250°C to obtain a low-MW PE having a density of 0.85W0.98 and a viscosity-average MW of 500W30,000.


Inventors:
GOUKO NOBUAKI
UEHARA YUMITO
MATSUDA YUKIMASA
Application Number:
JP1581283A
Publication Date:
August 15, 1984
Filing Date:
February 02, 1983
Export Citation:
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Assignee:
MITSUBISHI CHEM IND
International Classes:
C08F2/00; C08F2/38; C08F4/00; C08F4/60; C08F4/64; C08F10/02; (IPC1-7): C08F2/38; C08F4/64; C08F10/02
Attorney, Agent or Firm:
Hajime Hasegawa



 
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