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Title:
PRODUCTION OF MULTILAYERED FILM OF METAL OXIDE
Document Type and Number:
Japanese Patent JPS6451347
Kind Code:
A
Abstract:

PURPOSE: To prevent exfoliation of a multilayered film due to continuous or intermittent thermal shock by forming a layer consisting of at least one kind of oxide among SiO2, Al2O3, oxide of P and B on the surface of a glass substrate before the formation of an oxide multilayered film.

CONSTITUTION: For example, an infrared rays reflecting film 2 is formed on the surface of a tube or bulb 1 consisting of transparent quartz glass of a tungsten halogen lamp by a dipping calcination method using an organometallic compd. soln. for this purpose, a soln. of alkoxy silane in alcohol and a soln. of titanium alkoxide in alcohol are prepd. wherein each solute is polymerized to some degree, forming an SiO2 coating soln. and TiO2 coating soln., and a P compd. is incorporated into the SiO2 coating soln. In the first stage, an oxide layer 3 contg. P-contg. SiO2 is formed on a bulb 1 with said SiO2 on the surface after cleaning the surface, then a layer 21 of a highly refractive substance consisting of TiO2 as the first layer of a multilayered film is formed with the TiO2 soln. Also, a layer 22 of a low refractive substance consisting of P-contg.-SiO2 is formed similarly as the layer 3, and the layer 21 and the layer 22 are formed alternately to obtain thus a film 2.


Inventors:
HORIKOSHI SOICHIRO
Application Number:
JP20808187A
Publication Date:
February 27, 1989
Filing Date:
August 24, 1987
Export Citation:
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Assignee:
IWASAKI ELECTRIC CO LTD
International Classes:
B05D1/18; B05D1/38; B05D7/00; C03C17/34; G02B5/28; (IPC1-7): B05D1/18; B05D1/38; B05D7/00; C03C17/34; G02B5/28
Domestic Patent References:
JPS58221811A1983-12-23
JPS58137809A1983-08-16
JPS60130049A1985-07-11
JPS61101949A1986-05-20