PURPOSE: To obtain the titled emulsion having small pores in the interior, useful as a coating compound, etc. to provide a film of coating having improved opacifying properties, and improved physical properties, by subjecting a polymerizable vinyl monomer, etc. to emulsion polymerization in the presence of a water-insoluble nonpolymerizable solvent optionally in the presence of a polymerizable emulsion to become seed particles.
CONSTITUTION: (A) 0W90pts.wt. polymer emulsion obtained by subjecting (i) a polymerizable vinyl monomer [e.g., (meth)acrylic ester, etc.], and, if necessary, (ii) a polyfunctional crosslinkable monomer (e.g., ethylene glycol dimethacrylate, etc.), (B) 0.1W100pts.wt. water-insoluble nonpolymerizable solvent (e.g., aliphatic hydrocarbon solvent, etc.), (C) 100W10pts.wt. polymerizable vinyl monomer, and (D) 0W50pts.wt. polyfunctional monomer are subjected to emulsion polymerization, to give the aimed emulsion.
YOSHINO FUMIO
TABATA MICHINOBU
JPS4864187A | 1973-09-05 | |||
JPS5123994A | 1976-02-26 | |||
JPS51144394A | 1976-12-11 | |||
JP37013792A |