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Title:
PRODUCTION OF ORGANOPOLYSILIOXANE GUM CONTAINING RADIATION-CURABLE FUNCTIONAL GROUP
Document Type and Number:
Japanese Patent JP3328482
Kind Code:
B2
Abstract:

PROBLEM TO BE SOLVED: To obtain a high-molecular-weight organopolysiloxane gum capable of easily controlling degree of polymerization by mixing two specified silanol- group-containing organosilanes or organosiloxanes with a monoacyloxysilane and heating the mixture in the presence of an acid compound.
SOLUTION: This organopolysiloxane gum is produced by previously mixing at least one member selected from among silanol-group-containing organosilanes and organosiloxanes of formula I [wherein R1 and R2 are each a (substituted) monovalent hydrocarbon group; and (n) is 1-3,000] with at least one member selected from among silanol-group-containing organosiloxanes and organosiloxanes of formula II [wherein R3 is a (substituted) monovalent hydrocarbon group; R4 is a radiation-curable functional group; and (m) is 1-300] and a monoacyloxysilane of formula III [wherein R5 to R8 are each a (substituted) monovalent hydrocarbon group], and heating the resulting mixture in the presence of an acid compound of a pKa of 3 or below (desirably 0-3).


Inventors:
Masaharu Takahashi
Susumu Sekiguchi
Application Number:
JP29623495A
Publication Date:
September 24, 2002
Filing Date:
October 19, 1995
Export Citation:
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Assignee:
Shin-Etsu Chemical Co., Ltd.
International Classes:
C08G77/20; C08G77/06; C08G77/08; C08G77/16; C08G77/22; C08G77/28; C08K5/54; C08K5/548; C08L83/04; C08L83/06; C08L83/07; C08L83/08; (IPC1-7): C08G77/20; C08G77/28
Domestic Patent References:
JP4718998A
JP790083A
Attorney, Agent or Firm:
Shuji Iwamiya