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Patent Searching and Data


Title:
PRODUCTION OF PHENOLIC COMPOUND
Document Type and Number:
Japanese Patent JP03178947
Kind Code:
A
Abstract:

PURPOSE: To obtain a salicylic acid derivative by dissolving a 2,4-dialkylphenol and an alkali metal hydroxide in a lower alcohol, reacting, distilling out the lower alcohol and generated water to obtain an anhydrous alkali metal salt of the dialkylphenol and reacting CO2 with the resultant salt.

CONSTITUTION: A 2,4-dialkylphenol and NaOH, etc., (solid or aqueous solution) are dissolved in a lower alcohol (e.g. 1-4C alkanol) in an amount of 0.2-3wt. times to the dialkylphenol at 50-60°C and reacted, heated, then a mixture of distilled lower alcohol and water is removed to obtain an anhydrous alkali metal salt of the 2,4-dialkylphenol. Process of the distilling out is gradually performed in normal pressure for 2-5hr and further at 100-130°C inner temperature in reduced pressure. Next, CO2 is blown into the resultant anhydrous salt and reacted in a pressure from reduced pressure to near atmospheric pressure with keeping at 130-150°C to afford a 3,5-dialkylsalicyclic acid. Said compound is useful as color developer for pressure-sensitive recording paper.


Inventors:
Iwai, Masayuki
Yonezawa, Daigaku
Mishima, Akio
Application Number:
JP1990000095882
Publication Date:
August 02, 1991
Filing Date:
April 10, 1990
Export Citation:
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Assignee:
YOSHITOMI PHARMACEUT IND LTD
International Classes:
C07C37/66; C07C39/235; C07C51/15; C07C65/05; C07C37/00; C07C39/00; C07C51/15; C07C65/00; (IPC1-7): C07C37/66; C07C39/235; C07C51/15; C07C65/05