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Title:
PRODUCTION OF POLYCARBONATE
Document Type and Number:
Japanese Patent JPH01275630
Kind Code:
A
Abstract:

PURPOSE: To obtain a polycarbonate which is substantially colorless and excellent in hydrolysis resistance without using any heat stabilizer, by using phosgene prepared from carbon monoxide which a total sulfur concentration has decreased to a specified value in the production of a polycarbonate by reacting a dihydric phenol with phosgene.

CONSTITUTION: In the production of a polycarbonate by reacting a dihydric phenol with phosgene in the presence of a solvent, phosgene obtained by reacting carbon monoxide having a total sulfur concentration ≤30ppm. wol. with chlorine is used. Said carbon monoxide can be obtained by, for example, bringing carbon monoxide discharged from a producer into contact with a conversion catalyst to convert the contained sulfur compounds into hydrogen sulfide and further with an aqueous solution of a base such as calcium hydroxide, sodium carbonate or sodium hydroxide to remove hydrogen sulfide from it.


Inventors:
SHIMADA TSUNEO
MORI YOSHIO
YOSHINOUCHI TAKUYA
MITANI MASAHIKO
Application Number:
JP10421788A
Publication Date:
November 06, 1989
Filing Date:
April 28, 1988
Export Citation:
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Assignee:
TEIJIN CHEMICALS LTD
International Classes:
C08G64/20; C08G64/22; (IPC1-7): C08G63/62
Domestic Patent References:
JPS6369520A1988-03-29
JPS62297320A1987-12-24
Foreign References:
US3028365A1962-04-03
US3275601A1966-09-27
Attorney, Agent or Firm:
Maeda Junhiro