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Patent Searching and Data


Title:
PRODUCTION OF SILICONE BASED CONNAMIC ACID DERIVATIVE
Document Type and Number:
Japanese Patent JPH03204887
Kind Code:
A
Abstract:

PURPOSE: To obtain the title compound soluble in silicone oil, having excellent water resistance and oil resistance and having ultraviolet ray absorbing characteristics of wavelength in UV-B region.

CONSTITUTION: A compound (e.g. 3,4,5-trimethoxy-cinnamic acid sodium salt) expressed by formula I (X is alkoxy; a is 2 or 3; M is Na or K) is reacted with a compound [e.g. 3-(3-chloropropyl)heptamethylsiloxane] expressed by formula II [R1 is 1-4C alkyl, phenyl or trimethylsiloxy; R2 is bivalent hydrocarbon (containing hydrocarbon having hetero atom O) having at least one carbon; n is 0-3], preferably in an aprotic solvent such as DMF at 120-130°C to provide the aimed compound {e.g. [3-bis(trimethylsiloxy)methylsilylpropyl] 3,4,5- trimethoxycinnamate} expressed by formula III.


Inventors:
YOSHIDA MASASHI
NANBA TOMIYUKI
UEHARA KEIICHI
Application Number:
JP34383689A
Publication Date:
September 06, 1991
Filing Date:
December 28, 1989
Export Citation:
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Assignee:
SHISEIDO CO LTD
International Classes:
A61K8/00; A61K8/58; A61K8/89; A61Q17/04; A61K8/55; C07F7/18; C08L83/04; C09K3/00; (IPC1-7): A61K7/00; A61K7/44; C07F7/18; C09K3/00