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Patent Searching and Data


Title:
PRODUCTION OF VINYL CHLORIDE-BASED POLYMER
Document Type and Number:
Japanese Patent JP2531570
Kind Code:
B2
Abstract:

PURPOSE: To obtain a polymer having a uniform particle diameter with extremely rare fish eye while preventing scales from depositing by charging an emulsion of water/vinyl chlorides into water containing a suspension stabilizer, forming oil droplets containing water and then carrying out the (co)polymerization.
CONSTITUTION: An emulsion of water/vinyl chlorides containing a radical initiator, a surfactant, vinyl chloride and, as necessary, other copolymerizable vinyl monomers is prepared and charged into water containing a suspension stabilizer to form a water/vinyl chlorides/water type double emulsion comprising water- containing oil droplets dispersed in the continuous phase composed of water. The aqueous suspension (co)polymerization is then carried out. The emulsion of the water/vinyl chlorides is prepared at 0-40°C, especially 15-30°C temperature by using a surfactant having 1.5-9, especially 3-7 HLB. Sorbitan monopalmitate, stearic acid monoglyceride, etc., are used as the surfactant having 3-7 HLB.


Inventors:
TACHIBANA HIROMITSU
HAYASHI NOBUYUKI
ASADA NAONORI
MASUKO SEIICHI
Application Number:
JP8380393A
Publication Date:
September 04, 1996
Filing Date:
March 19, 1993
Export Citation:
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Assignee:
KANEGAFUCHI KAGAKU KOGYO KK
DENKI KAGAKU KOGYO KK
TOA GOSEI KK
MITSUI TOATSU KAGAKU KK
International Classes:
C08F2/32; C08F2/18; C08F2/20; C08F14/00; C08F14/06; (IPC1-7): C08F2/32; C08F2/20; C08F14/06
Attorney, Agent or Firm:
Ryoko Tsuji