Title:
REACTION METHOD AND NOVEL AZO COMPOUND USED IN THE SAME
Document Type and Number:
Japanese Patent JP2014148477
Kind Code:
A
Abstract:
PROBLEM TO BE SOLVED: To provide a reaction method in which a further easy-to-use oxidation-reduction condensation reaction can be realized.SOLUTION: When a stereospecific reaction by activation of an alcoholic hydroxy group is performed under the presence of an azo compound and triphenylphosphine, the azo compound containing an aryl group is used as the azo compound. An azo making catalyst is added to a reaction system, and the reaction can be performed while a reduced azo compound is performed by reoxidation by the azo making catalyst under the presence of oxygen. In addition, at a reaction initiation time, a hydrazine compound that is a reduction body of the azo compound is used instead of the azo compound, and can be made to function as the azo compound by the reoxidation.
Inventors:
TANIGUCHI TAKASHI
HIROSE DAISUKE
ISHIBASHI HIROYUKI
HIROSE DAISUKE
ISHIBASHI HIROYUKI
Application Number:
JP2013017504A
Publication Date:
August 21, 2014
Filing Date:
January 31, 2013
Export Citation:
Assignee:
UNIV KANAZAWA
International Classes:
C07C201/12; C07C205/57; C07C245/06; C07B61/00
Attorney, Agent or Firm:
Kimori An owner common
Sayuri Asaka
Sayuri Asaka