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Title:
REACTION MIXTURE FOR PREPARING CYCLOOLEFIN POLYMERS HAVING STRAINED RINGS
Document Type and Number:
Japanese Patent JPS6469612
Kind Code:
A
Abstract:

PURPOSE: To obtain efficiently polymers excellent in flexural elastic modulus, etc., by using 2,6-dihalo-4-alkylphenol as phenolic compounds to be used for metathesis polymerization having strained rings.

CONSTITUTION: The cycloolefin polymer is obtained by mixing metathesis polymer catalyst (ex.: tungsten catalyst) with 2,6-dihalo-4-1C to 4C alkylphenol (ex.:2,6-dibromo-4-methylphenol). Then, by contacting this reaction mixture with metathesis catalyst activators such as alkyl aluminum halide, etc., containing 1C to 10C alkyl groups and cycloolefin, with at least one type of cycloolefin (ex.: cyclopentadiene) having strained rings in the molar ratio range of cycloolefin: tungsten of about (1000-15000):1 at a temperature of about 30 to 100°C.


Inventors:
AANDOREA ERIZABESU MAATEIN
Application Number:
JP20748888A
Publication Date:
March 15, 1989
Filing Date:
August 23, 1988
Export Citation:
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Assignee:
HERCULES INC
International Classes:
C08F4/62; C08F10/14; C08F32/02; C08G61/08; (IPC1-7): C08F4/62; C08F32/02
Domestic Patent References:
JPS52130900A1977-11-02
JPS5450598A1979-04-20
Attorney, Agent or Firm:
Maeda Junhiro