Title:
ルテニウム錯体及びその製造方法並びにその用途
Document Type and Number:
Japanese Patent JP6456364
Kind Code:
B2
Abstract:
The present invention provides a novel ruthenium complex that is easy to produce and handle and that can be supplied relatively inexpensively, a method for producing this ruthenium complex, a method for producing alcohols and the like using this ruthenium complex as a catalyst, a method for producing carbonyl compounds using this ruthenium complex as a catalyst, and a method for producing N-alkylamine compounds using this ruthenium complex as a catalyst. The present invention pertains to a ruthenium complex represented by general formula (1) RuX 1 X 2 (PNP)(NHC) m (Solv) n (1) (in general formula (1), X 1 and X 2 each independently represent a monovalent anionic monodentate ligand; PNP represents a tridentate aminodiphosphine ligand, NHC represents an N-heterocyclic carbene derived from a nitrogen-containing heterocyclic ring, and Solv represents a coordinating solvent; and m represents an integer from 1 to 3, n represents an integer from 0 to 2, and 1 ¤ m + n ¤ 3.), a method for producing the same, a catalyst including the same, and methods for producing various organic compounds using this catalyst.
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Inventors:
Small size
Hideki Nara
Yuji Nakayama
Hideki Nara
Yuji Nakayama
Application Number:
JP2016515217A
Publication Date:
January 23, 2019
Filing Date:
April 24, 2015
Export Citation:
Assignee:
Takasago International Corporation
International Classes:
C07F15/00; B01J31/24; B01J37/04; C07C29/141; C07C29/145; C07C29/149; C07C31/20; C07C33/22; C07C35/08; C07C209/18; C07C211/48; C07D213/30; C07F9/50
Domestic Patent References:
| JP2010527316A |
Foreign References:
| WO2011048727A1 |
Other References:
DEMOTT, Jessica C. et al.,Frustrated Lewis pair-like splitting of aromatic C-H bonds and abstraction of halogen atoms by a cat,Chemical Science,2013年,4(2),642-649
PRECHTL, Martin H. G. et al.,Ruthenium dihydrogen complex for C-H activation: catalytic H/D exchange under mild conditions,European Journal of Inorganic Chemistry,2008年,(22),3493-3500
BIANCHINI, Claudio et al.,Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II),Inorganica Chimica Acta,1998年,272(1,2),1-3
GREGOR, Lauren C. et al.,Heterolytic splitting of H-X bonds at a cationic (PNP)Pd center,Dalton Transactions,2010年,39(13),3195-3202
BIANCHINI, Claudio et al.,A novel reaction of coordinated vinylidenes: coupling with hydrogen sulfide to give a η1-thioaldehy,Journal of the Chemical Society, Chemical Communications,1994年,(19),2219-20
PRECHTL, Martin H. G. et al.,Ruthenium dihydrogen complex for C-H activation: catalytic H/D exchange under mild conditions,European Journal of Inorganic Chemistry,2008年,(22),3493-3500
BIANCHINI, Claudio et al.,Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II),Inorganica Chimica Acta,1998年,272(1,2),1-3
GREGOR, Lauren C. et al.,Heterolytic splitting of H-X bonds at a cationic (PNP)Pd center,Dalton Transactions,2010年,39(13),3195-3202
BIANCHINI, Claudio et al.,A novel reaction of coordinated vinylidenes: coupling with hydrogen sulfide to give a η1-thioaldehy,Journal of the Chemical Society, Chemical Communications,1994年,(19),2219-20
Attorney, Agent or Firm:
Takuro Saeki
Nakamura Tadashi Exhibition
Naoko Ushiyama
Yuko Saeki
Nakamura Tadashi Exhibition
Naoko Ushiyama
Yuko Saeki