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Title:
ルテニウム錯体
Document Type and Number:
Japanese Patent JP6388803
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide a ruthenium complex which can be useful as a reduction catalyst applicable to industrial production.SOLUTION: Provided is a ruthenium complex represented by formula (I): Ru(L)(L)(Px)(Z) (I) [Land Lare each independently an anionic ligand; Land Lmay together form a bidentate or higher anionic ligand; Px is a phosphine ligand; n is an integer of 1 or 2; Z is a ligand having a structure where a heterocycle A and heterocycle B are bound by a single bond; in the heterocycle A, at least one of atoms adjacent to an atom bound to the heterocycle B through a single bond is a nitrogen atom, and there is no N-H bond in the heterocycle A; the heterocycle B is 1-methyl-benzimidazol-2-yl, 1-methyl-pyrazol-3-yl, 1-methyl-imidazol-2-yl, 1,5-dimethyl-1,2,4-triazol-3-yl, and the like].

Inventors:
Hirohito Ooka
Tsutomu Inoue
Application Number:
JP2014144950A
Publication Date:
September 12, 2018
Filing Date:
July 15, 2014
Export Citation:
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Assignee:
Nippon Soda Co., Ltd.
International Classes:
C07D401/04; B01J31/24; C07C29/145; C07C33/22; C07D403/04; C07D413/04; C07D417/04; C07D471/04
Domestic Patent References:
JP2012104509A
JP2013513641A
Foreign References:
CN102060877A
US20120323007
WO2010036765A1
Other References:
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TUNG, Yung-Liang, et al.,Advanced Materials,2005年,17(8),pp. 1059-1064
YE, Wenjing, et al.,Chemistry A European Journal,2011年,17,pp. 4737-4741
MULLER, Keven, et al.,Chemistry A European Journal,2013年,19,pp. 7825-7834
JOZAK, Thomas, et al.,European Journal of Inorganic Chemistry,2010年,32,pp. 5135-5145
CUERVO, Dario, et al.,Chemistry A European Journal,2004年,10,pp. 425-432
ZENG, Fanlong, et al.,Organometallics,2008年,27(13),pp. 2898-2901
MAJI, Milan, et al.,Journal of Coordination Chemistry,2001年,54(1),pp. 13-24
XIANG, Jing, et al.,Zeitschrift fur anorganische und allgemeine Chemie,2013年,(3-4),pp. 606-610
Attorney, Agent or Firm:
Tadayuki Kikuma