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Title:
Si-based alloy negative electrode material
Document Type and Number:
Japanese Patent JP6322362
Kind Code:
B2
Abstract:
Disclosed is a Si-based alloy anode material for lithium ion secondary batteries. This Si-based alloy anode material comprises an alloy phase composed of a Si principal phase comprising Si and a compound phase comprising two or more elements. The two or more elements comprise a first additional element A being at least one selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Nb and Mg and a low-melting second additional element B being at least one selected from the group consisting of S, Se, Te, Sn, In, Ga, Pb, Bi, Zn, Al and Ag. This compound phase comprises (i) a first compound phase comprising Si and the first additional element A; a second compound phase comprising the first additional element A and the second additional element B; and one or both of a third compound phase comprising two or more of the second additional elements B and a single phase of the second additional element B, or, alternatively, comprises (ii) a compound phase comprising Si and the first additional element A; and one or both of a compound phase comprising two or more of the second additional elements B and a single phase of the second additional element B. The Si principal phase has an average minor axis width of 4µm or less. This anode material of the present invention enables provision of secondary batteries having satisfactory performances both in charge-discharge capacity and cycle life.

Inventors:
Hirono Yuki
Tetsuro Kaya
Toshiyuki Sawada
Application Number:
JP2012276615A
Publication Date:
May 09, 2018
Filing Date:
December 19, 2012
Export Citation:
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Assignee:
Sanyo Special Steel Co., Ltd.
International Classes:
H01M4/38; C22C9/00
Domestic Patent References:
JP2001256974A
JP2010519718A
JP2008135364A
JP2005011650A
JP2009521792A
JP2010040279A
JP4739462B1
JP4865105B1
JP2012150910A
JP2012178344A
JP2006185716A
JP2011032541A
Foreign References:
WO2010132279A1
WO2012008540A1
Attorney, Agent or Firm:
Patent business corporation Yuko patent office