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Title:
SILICONE-MODIFIED AQUEOUS DISPERSION AND WATER-BASED COATING COMPOSITION USING THE SAME
Document Type and Number:
Japanese Patent JP2003321512
Kind Code:
A
Abstract:

To provide a silicone-modified aqueous dispersion in good polymerization stability with few coarse particles where the emulsion polymer and the silicone are in a homogeneous state, and to provide e.g. a water-based coating using the aqueous dispersion.

The aqueous dispersion is obtained by the following steps. (1) Emulsion copolymer particles are prepared by carrying out an emulsion copolymerization between 0.5-10 pt(s).wt. of a 3-8C unsaturated carboxylic acid compound, 10-99.5 pts.wt. of an acrylic 1-3C alkyl ester and 89.5-0 pt(s).wt. of an ethylenically unsaturated monomer, and (2) in the presence of the emulsion copolymer particles, an alkoxysilane compound is added at ≤30°C in the proportions described in (i) and (ii) below followed by temperature rise to 60-90°C to carry out a condensation reaction with the emulsion copolymer particle: (i) 4-30 wt. times the 3-8C unsaturated carboxylic acid compound, and (ii) 0.02-0.75 wt.% time the emulsion copolymer nonvolatiles. The water-based coating comprising the aqueous dispersion is also provided.


Inventors:
NAKANISHI KENICHI
HARADA AKIO
Application Number:
JP2002130021A
Publication Date:
November 14, 2003
Filing Date:
May 01, 2002
Export Citation:
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Assignee:
SHOWA HIGHPOLYMER
International Classes:
C09D5/00; C08F8/42; C08F220/12; C09D133/00; C09D143/04; C09D183/04; (IPC1-7): C08F8/42; C08F220/12; C09D5/00; C09D133/00; C09D143/04; C09D183/04
Attorney, Agent or Firm:
Soga Doteru (6 people outside)



 
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