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Title:
SOLID CATALYST FOR OLEFIN POLYMERIZATION
Document Type and Number:
Japanese Patent JPH09176224
Kind Code:
A
Abstract:

To obtain an olefin polymer having a high bulk density and excellent powder properties by using a specific solid catalyst (D) for olefin polymerization comprising a group IV transition metal compound catalyst component (A), an aluminoxane catalyst component (B) and a microparticulate organic compound/inorganic compound support (C).

Component A is represented by the formula: R1kR2lR3mR4nZr (wherein R1 is a cycloalkadienyl; R2 to R4 are each a cycloalkadienyl, an aryl, an alkyl, a cycloalkyl, an aralkyl, a halogen, H, ORa, SRb, NRc2 or PRd2; Ra, Rb, Rc or Rd are each a hydrocarbon group or silyl; k≥1, and k+l+m+n=4). Component B is represented by formula I or II (wherein R is a hydrocarbon group; and (m) is a number of 2 or greater). One half (0.5) to 500mg atom of Zr and 5-50,000mg atom of Al are present per 100g of component C. Component C used is made of a polyolefin or SiO2. Catalyst D has a mean particle diameter of 5-200μm and shows high polymerization activity in homopolymerization or copolymerization.


Inventors:
KIOKA MAMORU
KASHIWA NORIO
Application Number:
JP4145597A
Publication Date:
July 08, 1997
Filing Date:
February 10, 1997
Export Citation:
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Assignee:
MITSUI PETROCHEMICAL IND
International Classes:
C08F4/60; C08F4/64; C08F4/642; C08F4/659; C08F4/6592; C08F10/00; C08F110/02; C08F210/16; (IPC1-7): C08F4/642; C08F10/00
Domestic Patent References:
JPS61108610A1986-05-27
Attorney, Agent or Firm:
Heiyoshi Odashima