To provide a separation/sorting recovery method of a multilayer resin structure capable of extremely easily separating, sorting and recovering the multilayer resin structure comprising different kinds of resins not depending on winnowing in a sorting recovery method for a multilayer resin structure.

In the method, after the respective resin components of the multilayer resin structure comprising at least two kinds of resin component A and resin component B not chemically adhered are crushed, separated and charged, the resin components A, B are separated, sorted and recovered by ranking difference of electrostatic charge row of the resin components respectively.