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Title:
SUBSTITUTED ALPHA-PYRONES AND NAPHTHOQUINONES
Document Type and Number:
Japanese Patent JPH0225480
Kind Code:
A
Abstract:

NEW MATERIAL: A compd. represented by formula I [wherein R1 is CF3 or COOR3 (wherein R3 is a group obtained by removing OH from 1-18C alcohol), R2 is F, Br, C, CN, CF3, 1-18C alkyl and alkoxy, 1-18C alkylthio, 6-1C aryl, 7-24C alkaryl, 7-12C aralkyl or 2-24C secondary amine].

EXAMPLE: Ethyl 4-ethoxy-2-oxo-2H-pyran-5-carboxylate.

USE: A raw material for producing novel naphthoquinone represented by formula II being an intermediate for producing substituted anthracene-5,12-dione used in substituted tetrathiotetracene and tetraselenotetracene producing a conductive charge moving complex using an electron acceptor.

PROCESS: A novel compd. represented by formula III (wherein R4 is 1-4C alkyl) is cyclized in the presence of anhydrous strong acid such as formic anhydride or polyphosphoric acid at 50-250°C without using a solvent to obtain the compd. represented by formula I.


Inventors:
BURATEISURABU KUBITA
MARUKUSU BAUMAN
BUARUTAA FUISHIYAA
KAARU DABURIYU MAIERU
TOOMASU ARUMENDEINGERU
Application Number:
JP13291589A
Publication Date:
January 26, 1990
Filing Date:
May 29, 1989
Export Citation:
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Assignee:
CIBA GEIGY AG
International Classes:
C07D309/30; B05D1/20; C07C45/00; C07C50/24; C07C67/00; C07C69/95; C07D309/38; C07F7/08; C07F7/18; C08G61/12; C09K9/02; H01B1/12; (IPC1-7): C07C50/24; C07C69/95; C07D309/30; C07F7/08; C07F7/18; C09K9/02
Attorney, Agent or Firm:
Hajime Tsukuni (1 person outside)