NEW MATERIAL: A compd. represented by formula I [wherein R1 is CF3 or COOR3 (wherein R3 is a group obtained by removing OH from 1-18C alcohol), R2 is F, Br, C, CN, CF3, 1-18C alkyl and alkoxy, 1-18C alkylthio, 6-1C aryl, 7-24C alkaryl, 7-12C aralkyl or 2-24C secondary amine].
EXAMPLE: Ethyl 4-ethoxy-2-oxo-2H-pyran-5-carboxylate.
USE: A raw material for producing novel naphthoquinone represented by formula II being an intermediate for producing substituted anthracene-5,12-dione used in substituted tetrathiotetracene and tetraselenotetracene producing a conductive charge moving complex using an electron acceptor.
PROCESS: A novel compd. represented by formula III (wherein R4 is 1-4C alkyl) is cyclized in the presence of anhydrous strong acid such as formic anhydride or polyphosphoric acid at 50-250°C without using a solvent to obtain the compd. represented by formula I.
MARUKUSU BAUMAN
BUARUTAA FUISHIYAA
KAARU DABURIYU MAIERU
TOOMASU ARUMENDEINGERU