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Title:
SUBSTITUTED BENZENEDITHIOL METAL COMPLEX AND ITS PRODUCTION
Document Type and Number:
Japanese Patent JP2000226377
Kind Code:
A
Abstract:

To obtain the subject new compound capable of functioning not only as a single oxygen quencher but also as an optical information medium itself.

This compound is represented by formula I [R is a (substituted) piperazinyl; M is a transition metal; A+ is a quaternary ammonium or a quaternary phosphonium] such as a compound of formula II. The compound of formula I is obtained by reacting a 3,4-dihalogenobenzenesulfonyl chloride with piperazine or a substituted piperazinyl compound to synthesize a compound of formula III (X1 and X2 are each chlorine or the like) [e.g. 4-(N- methylpiperazinylsulfonyl)-1,2-dichlorobenzene], reacting the compound of formula III with sodium hydrosulfide in the presence of iron powder and sulfur powder as catalysts and converted the obtained product into a compound of formula IV and further reacting this compound with a transition metal salt [e.g. nickel chloride (II) hexahydrate] and a quaternary ammonium or a quaternary phosphonium salt (e.g. tetrabutylammonium bromide).


Inventors:
HIRAKO KAZUYOSHI
KIMURA SATOSHI
SUZUKI MICHIO
HATA HIROYUKI
Application Number:
JP11387899A
Publication Date:
August 15, 2000
Filing Date:
April 21, 1999
Export Citation:
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Assignee:
SUMITOMO SEIKA CHEMICALS
International Classes:
C07D295/22; C07D239/42; C07D241/04; C07F1/08; C07F9/54; C07F15/04; (IPC1-7): C07D241/04; C07D239/42; C07D295/22; C07F9/54