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Title:
SURFACE TREATED ELECTROLYTIC COPPER FOIL AND COPPER CLAD LAMINATE OBTAINED BY USING THE SAME
Document Type and Number:
Japanese Patent JP2013019056
Kind Code:
A
Abstract:

To provide a surface treated electrolytic copper foil which has a low profile on an equal or higher level as compared with a low-profile surface treated electrolytic copper foil which has been supplied on the conventional market and is small in waviness which affects the linearity of wiring, and to provide a process for producing the surface treated electrolytic copper foil.

In the surface treated electrolytic copper foil, on the face of adhesion to an insulating layer constituent material, the maximum level difference of elevation of waviness (Wmax) is 0.05 μm to 0.7 μm, the maximum difference of elevation of irregularities (PV) is 0.05 to 1.5 μm, and the surface roughness (Rzjis) is 0.1 μm to 1.0 μm. The electrolytic copper foil used in the production of the surface treated electrolytic copper foil is produced by electrolysis under electrolytic conditions of current density on at least two different levels from continuous first step electrolysis to nth step electrolysis, using a sulfuric acid-based copper electrolysis solution, prepared by adding 3-mercapto-1-propanesulfonic acid or bis(3-sulfopropyl)disulfide, a quaternary ammonium salt polymer having a cyclic structure, and chlorine, and by using a cathode having a small surface roughness.


Inventors:
DOBASHI MAKOTO
MATSUDA MITSUYOSHI
TOMONAGA SAKIKO
SAKAI HISAO
SAKATA TOMOHIRO
YOSHIOKA ATSUSHI
NISHIKAWA SUSUMU
TAGUCHI TAKEO
Application Number:
JP2012231519A
Publication Date:
January 31, 2013
Filing Date:
October 19, 2012
Export Citation:
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Assignee:
MITSUI MINING & SMELTING CO
International Classes:
C25D1/04; C25D7/06; H05K1/09
Domestic Patent References:
JP2004263296A2004-09-24
JP2004263289A2004-09-24
JP2005015861A2005-01-20
JPS502378B11975-01-25
Foreign References:
WO2003096776A12003-11-20
Attorney, Agent or Firm:
Katsuhiro Yoshimura