To obtain a chromium-free surface treated steel sheet exhibiting excellent corrosion resistance and scratch resistance.
As a first layer film, an organic-inorganic composite layer in which the surface layer of a plating film is made inactive by a surface treatment composition containing a water base resin, a phosphoric compound and a silane coupling agent is formed as a second layer film, an organic film combining firm adhesion and lubricity in between the first layer film is formed by a coating material film composition containing a water soluble or water dispersible urethane modified resin, a curing agent, silica and wax in specified ratios, and, by the two layer film structure, excellent corrosion resistance and scratch resistance are realized.
HIGAI KAZUHIKO
OGATA HIROYUKI
YAMAJI TAKAFUMI
JPH10237478A | 1998-09-08 | |||
JPH11106945A | 1999-04-20 | |||
JP2000054186A | 2000-02-22 | |||
JP2003055790A | 2003-02-26 | |||
JP2000355790A | 2000-12-26 | |||
JP3464652B2 | 2003-11-10 |
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