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Title:
SYNTHESIS OF ALDEHYDE
Document Type and Number:
Japanese Patent JP2002012571
Kind Code:
A
Abstract:

To provide a method for producing corresponding aldehydes in high yield and selectivity by reacting a carboxylic acid or an ester thereof with hydrogen.

This method for synthesizing the aldehyde of general formula I [R1 to R3 are each hydrogen, a 1-6C alkyl, a 3-8C cycloalkyl, an aryl, a 7-12C alkylphenyl or a 7-12C phenylalkyl, or R1 and R2 may form a 3- to 7-membered alicyclic ring by bonding to each other] comprises reacting the carboxylic acid or the ester thereof, represented by general formula II [R1 to R3 are same as the above; R4 is hydrogen, a 1-6C alkyl, a 3-8C cycloalkyl, an aryl, a 7-12C alkylphenyl or a 7-12C phenylalkyl] with the hydrogen in a vapor phase in the presence of a catalyst containing zirconium oxide and one or more kinds of lanthanoid elements in the presence of water.


Inventors:
MERGER MARTIN
GERLACH TILL
SCHWAB EKKEHARD
WULFF-DOERING JOACHIM
MUHLER MARTIN
HAGEN VOLKER
Application Number:
JP2001136616A
Publication Date:
January 15, 2002
Filing Date:
May 07, 2001
Export Citation:
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Assignee:
BASF AG
International Classes:
B01J23/10; C07B61/00; C07C45/41; C07C47/02; C07C47/11; C07C221/00; C07C223/02; B01J21/06; (IPC1-7): C07C45/41; B01J23/10; C07C47/02; C07C47/11
Attorney, Agent or Firm:
Yusuke Hiraki (1 person outside)