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Title:
THERMAL POLYMERIZATION OF DICYCLOPENTADIENE
Document Type and Number:
Japanese Patent JPH0848723
Kind Code:
A
Abstract:

PURPOSE: To obtain a dicyclopentadiene resin having a relatively low molecular weight and a relatively narrow molecular weight distribution by heating a reaction material containing a dicyclopentadiene monomer in the presence of a strong acid under specified conditions.

CONSTITUTION: A reaction material containing a (di)cyclopentadiene monomer is heated at a temperature of about 240 to about 320°C for a time sufficient to form a dicyclopentadiene oligomer resin showing a weight-average molecular weight in the presence of a strong acid and in the range of about 260 to about 1,000 and a polydispersity index of about 2.3 or below desirably under the autogenous pressure in a sealed container. The strong acid desirably used is a Bronsted acid selected among hypophosphorous acid, p-toluenesulfonic acid, hydrochloric acid, hydrogen iodide, phosphoric acid, methanesulfonic acid, and a mixture thereof and is present in a concentration of about 0.05 to about 1.0 wt.% based on the total weight of the reaction mixture.


Inventors:
SHIIADOA JIEI UIRIAMUZU
Application Number:
JP812195A
Publication Date:
February 20, 1996
Filing Date:
January 23, 1995
Export Citation:
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Assignee:
ARIZONA CHEM
International Classes:
C08F32/00; C08F32/06; C08F32/08; C09D11/02; C09D11/10; C09D145/00; C09D193/00; C08F2/38; C09D193/04; C09J121/00; C09J123/02; C09J123/08; C09J145/00; (IPC1-7): C08F32/06; C08F2/38; C09D11/10; C09D145/00; C09D193/04; C09J123/08; C09J145/00
Attorney, Agent or Firm:
Kyozo Yuasa (6 people outside)