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Title:
【発明の名称】変性ポリビニルアルコール
Document Type and Number:
Japanese Patent JP2736747
Kind Code:
B2
Abstract:
PURPOSE: To obtain the subject alcohol, containing a specific structural unit, excellent in dispersing performances, having resistance to polyvalent metallic ions and excellent in dehydration reducing performances and useful as a dispers ing agent or a muddy water regulator for drilling. CONSTITUTION: This modified polyvinyl alcohol comprises a structural unit of formulas I to III (R is H or CH3 ; M<1> and M<2> are each H, an alkali, metal, ammonium, an alkylammonium or an alkanolammonium) and has 0.5-30.0mol% content of the unit of formula I, 99.4-50.0mol% content of unit of formula II, 0.1-20.0mol% content of unit of formula III, 0.6-50.0mol% total content of the units of formulas I and III, 3000-400000 weight-average molecular weight and preferably <5.0mol% content of unit of formula IV. Furthermore, the modified polyvinyl alcohol is preferably obtained by, e.g. carrying out the Michael addition of acrylamide to PVA in the presence of an alkaline catalyst, then hydrolyzing the resultant compound and further performing the Michael addition, etc., of a 2-acrylamido-2-methylpropane-3-sulfonate thereto.

Inventors:
YADA AKIRA
KITADA AKIRA
MORI YOSHUKI
NISHIGUCHI HIROSHI
Application Number:
JP22785994A
Publication Date:
April 02, 1998
Filing Date:
September 22, 1994
Export Citation:
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Assignee:
DAIICHI KOGYO SEIYAKU KK
International Classes:
C09K8/04; C09K23/52; C08F8/34; (IPC1-7): C08F8/34; B01F17/52; C09K7/02
Domestic Patent References:
JP1228528A
JP63243190A
JP770230A
JP60106875A
Other References:
【文献】米国特許5104933(US,A)
Attorney, Agent or Firm:
Hitoko Tsuda (2 outside)