PURPOSE: To reduce NO2 by NH3 in a single stage without by-producing N2O by using a high-activity catalyst for the reduction of NO2 and N2O with NH3.
CONSTITUTION: The alkali metal or alkaline-earth metal of natural or synthetic zeolite is substituted with hydrogen and/or iron to obtain a catalyst. The catalyst is active not only to the denitration of N2O by reduction with ammonia but also to the denitration of NO2. The so-called high-silica zeolite having ≥3 ratio of SiO2/Al2O3 can be suitably used as the zeolite. The substitution is carried out by immersing zeolite into an aq. soln. of hydrochloric acid, NH4Cl, FeCl3, or ferric nitrate, and then calcining at 500°C to manufacture the catalyst. The amt. of NH3 injected during the nitration is preferably regulated to ≥1.34 NH3/NOx, especially to ≥1.6.
KONISHI KUNIHIKO
OOTA MASAO
JPS57140628A | 1982-08-31 | |||
JPS51147470A | 1976-12-17 | |||
JPS50160166A | 1975-12-25 |
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