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Title:
【発明の名称】焼却灰からの鉛及び亜鉛の分別回収方法
Document Type and Number:
Japanese Patent JP2972524
Kind Code:
B2
Abstract:
PURPOSE:To successively precipitate the lead and zinc in an incinerated ash as the sulfides and to fractionally recover the lead and zinc efficiently by supplying sodium sulfide to a soln. containing eluted heavy metals from the ash and regulating the pH of the soln. CONSTITUTION:The incinerated ash of refuse, etc., is mixed with hydrochloric acid to elute the heavy metals from the ash, and solid is separated from liq. to prepare the soln. of the heavy metals. Sodium sulfide or gaseous hydrogen sulfide is supplied while agitating the soln., and the pH is regulated to 0.4-1.2 to precipitate lead as the sulfide, which is separated and recovered. Sodium sulfide or gaseous hydrogen sulfide is then supplied to the soln. separated from the precipitate, and the pH is regulated to >=2 to precipitate the zinc as the sulfide, which is separated and recovered. Consequently, lead and zinc are fractionally separated from the incinerated ash efficiently, and the waste water generated in the recovery is made harmless.

Inventors:
MIZUKAMI SHUNICHI
KINARI TOSHIHIDE
KAMEOKA YOSHIBUMI
ITO TADASHI
KAWABATA HIROAKI
Application Number:
JP17828994A
Publication Date:
November 08, 1999
Filing Date:
July 29, 1994
Export Citation:
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Assignee:
KOBE SEIKOSHO KK
International Classes:
C22B13/00; C22B19/30; B09B3/00; (IPC1-7): C22B13/00; B09B3/00; C22B19/30
Domestic Patent References:
JP4718705A
JP49113703A
JP59126729A
JP61136639A
JP4265189A
JP7109533A
Attorney, Agent or Firm:
Akeda Kan