NEW MATERIAL:Compounds of formula I , wherein X, X' are each halogen; Y, Y' are each H, sulfo, a group of formula II or III (wherein Z is a group which can be removed by the action of an alkali), etc.; A, A' are each (substd.) phenylene, naphthylene; R1, R2 R'1 R'2 are each H, (substd.) lower alkyl; B, B' are each phenylene which may be substituted with lower alkyl, lower alkoxy, ureido, etc.
EXAMPLE: Disazo dye of formula IV.
USE: Disazo dyes which dye or print cellulose fiber materials, fibrous polyamides and polyurethanes yellow.
PREPARATION: 4-Amino-4'-nitrostilbene-2,2'-disulfonic acid is diazotized and then coupled with an aniline derivative. The resulting monoazo compd. of formula Vand a compd. of formula VI are condensed with a trihalogenotriazine in any order. The condensate is reduced with sodium sulfide, diazotized and coupled with an aniline derivative to obtain the disazo compd. of formula VII.
KAYANE YUTAKA
TAKAHASHI SHIYOU
HARADA NAOKI
OMURA TAKASHI