Title:
遷移金属錯体
Document Type and Number:
Japanese Patent JP5065886
Kind Code:
B2
Abstract:
A transition metal complex which is a bis-arylimine pyridine MXn complex or a [bis-arylimine pyridine MXp+][NC-]q complex comprising a bis-arylimine pyridine ligand and M is a transition metal atom; n matches the formal oxidation state of the transition metal atom M; X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; NC- is a non-coordinating anion; and p+q matches the formal oxidation state of the transition metal atom M. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co-)oligomerization, polymerization and dimerization reactions.
Inventors:
De Bourg, Eritsk Johannes Maria
Juan del Haden, Harry
On, Quotsk Ann
Smith, Johann Paul
Juan Zon, Ally
Juan del Haden, Harry
On, Quotsk Ann
Smith, Johann Paul
Juan Zon, Ally
Application Number:
JP2007504414A
Publication Date:
November 07, 2012
Filing Date:
March 22, 2005
Export Citation:
Assignee:
Ciel International Research Mart Shats Pay BV
International Classes:
C07D213/53; B01J31/22; C07C2/32; C07C11/02; C07D401/04; C07F11/00; C07F13/00; C07F15/00; C07F15/02; C07F15/06; C08F10/00; C07B61/00
Domestic Patent References:
| JP2002528573A | ||||
| JP2002524567A | ||||
| JP2001515930A |
Foreign References:
| CN1403424A | ||||
| WO2002000339A1 | ||||
| WO2003011876A1 | ||||
| US20030144438 |
Other References:
MORALE, F.,Columnar mesomorphism from hemi-disklike metallomesogens derived from 2,6-bis[3',4',5'-tri(alkoxy)phenyliminomethyl]pyridines (L): Crystal and molecular structures of [M(L)Cl2] (M=Mn, Ni, Zn),Chemistry A - European Journal,2003年,9(11),p. 2484-2501
Esteruelas, M. A.,Preparation, Structure, and Ethylene Polymerization Behavior of Bis(imino)pyridyl Chromium(III) Complexes,Organometallics,2003年,22(3),p. 395-406
Esteruelas, M. A.,Preparation, Structure, and Ethylene Polymerization Behavior of Bis(imino)pyridyl Chromium(III) Complexes,Organometallics,2003年,22(3),p. 395-406
Attorney, Agent or Firm:
Yoshio Kawaguchi
Makoto Ono
Chihiro Watanabe
Kenkyo Kanayama
Katsuma Osaki
Mitsuaki Tsubokura
Makoto Ono
Chihiro Watanabe
Kenkyo Kanayama
Katsuma Osaki
Mitsuaki Tsubokura